Comments on: Reagent Friday: Raney Nickel https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/ Sun, 17 Apr 2022 00:53:45 +0000 hourly 1 https://wordpress.org/?v=6.6.2 By: Grace https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-624954 Sun, 17 Apr 2022 00:53:45 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-624954 what is the mechanism for a cyclic thioacetal to an alkane?

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By: ASHUTOSH P https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-572939 Thu, 12 Dec 2019 07:35:54 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-572939 Fantastic work

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-568690 Wed, 23 Oct 2019 17:50:44 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-568690 In reply to Henry.

Yes, although it requires a high pressure of hydrogen gas.

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By: Henry https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-568457 Mon, 21 Oct 2019 08:09:10 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-568457 Can raney nickel reduce carbonyl compounds,carboxylic acids and esters?

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-564424 Wed, 18 Sep 2019 19:55:47 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-564424 In reply to Don.

The higher the pressure of H2, the faster the reaction will occur. Essentially you’re adding more “equivalents” of H2 and forcing the adsorption of H2 on to the active sites of the metal, speeding up the reaction (which occurs on the metal surface)

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-563279 Thu, 05 Sep 2019 18:47:39 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-563279 In reply to Carlos.

When I used it personally it did not appear to be reusable in any way. I ended up with green wastewater after destruction of excess reagent with acid. Nickel is not nearly as bad as chromium, but proper waste procedures should be followed.

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-563278 Thu, 05 Sep 2019 18:45:55 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-563278 In reply to Harry.

Darn it. Thank you.

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-563277 Thu, 05 Sep 2019 18:45:45 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-563277 In reply to Atul Sharma.

Yes, at high enough pressure.

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-563276 Thu, 05 Sep 2019 18:45:35 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-563276 In reply to vishnu.

With enough pressure, Raney Nickel can reduce carbonyls. You’re probably looking at at least 1000 psi, though.

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/09/30/reagent-friday-raney-nickel/#comment-563275 Thu, 05 Sep 2019 18:44:45 +0000 https://www.masterorganicchemistry.com/?p=2365#comment-563275 In reply to Chembuddy.

If it’s just NO2 to amine without touching the alkene, just use Sn and HCl.

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